Nano-Grid[n]arenes: A Diverse Platform of
Covalently Hierarchical Meta-molecules
Volume 1 - Issue 4
Linghai XIE*
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- Center for Molecular Systems & Organic Devices, Nanjing University of Posts & Telecommunications, China
*Corresponding author:
Linghai XIE, Center for Molecular Systems & Organic Devices (CMSOD), Institute of Advanced Materials (IAM),
Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing, 210023, China
Received: February 06, 2018; Published: February 16, 2018
DOI: 10.32474/AOICS.2018.01.000118
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Abstract
In the background of the era of consciousness (EOC) from
carbon to robot, we proposed an alternative way via the nanoarchitectures
to challenge suspended issues from plastic electronics.
Covalent meta-molecules with the features of structural diversity,
hierarchy and cross-scale have absolute advantages to decode the
universe law of matter and to explore the advanced materials. In
the past decade, we focus on a versatile C (sp3)- C (sp2) reaction
of fluorenol’sFrediel-Crafts protocol (FOH’s FCP) [1] as a tool of
molecular installing technology, associated with the Pd-catalyzed
(sp2)- C (sp2) coupling reaction such as Suzuki cross-coupling
reaction. A series of the complex di aryl fluorine’s (CDAFs), have
been synthesized, including small molecules, polymers, as well as
covalent nanostructures via the An+Bn and/ or Ann modes where
A represents for fluorine’s (from Alcohol) and Before benzene
substrates [2-8]. Recently, we discoverednano-gridarenes that
is a huge family of organic unit nanogrids [9], multigrids [10] as
well as polygrids [11] after the exploration of fluorine-based nano
synthesis ten year age [12]. Grid polymers serve as the advanced
soluble nanopolymers with potential application of light-emitting
diodes, lasers, solar cells and memory [13].
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